UiO-66 series metal-organic frameworks(MOF) were synthesized with zirconium chloride (ZrCl4) and 1,4-benzenedicarboxylic acid (H2BDC) which different functional groups were employed in hydrothermal condition modified by acetic acid in dimethyl formamide (DMF) solution.The CO2 and CO sorption was tested which indicated that the highest uptake of CO2 belonged to UiO-66-NH2 which the corresponding value was 100.14cm3/g,otherwise the uptake of CO was 17.69cm3/g,which had good adsorption property for CO2.
[1] Sanz-Pérez E S,Murdock C R,Didas S A,et al.Direct capture of CO2 from ambient air[J].Chemical Reviews,2016,116(19):11840-11876.
[2] U.S.Department of Energy.Materials for separation technologies:report of energy and emission reduction opportunities[R].Oak Ridge:Oak Ridge National Laboratory,TN,USA 2005.
[3] Sato H,Kosaka W,Matsuda R,et al.Self-accelerating CO sorption in a soft nanoporous crystal[J].Science,2014,343(6167):167-170.
[4] Cavka J H,Jakobsen S,Olsbye U,et al.A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability[J].Journal of the American Chemical Society,2008,130(42):13850-13851.
[5] 牛照栋,关清卿,陈秋玲,等.膦酸类金属-有机骨架材料对CO2的吸附性能研究进展[J].化工进展,2017,36(5):1782-1790.
[6] 张伊,顾奕奕,陈云琳,等.掺杂金属离子对MOF-5吸附甲烷分子的影响[J].化工新型材料,2015,43(2):93-96.
[7] Kitagawa S,Kitaura R,Noro.Functional porous coordination polymers[J].Angew Chem Int Ed,2004,43(8):2334-2375.
[8] Wu Chuande,Hu Aiguo,Zhang Lin.A homochiral porous metal-organic framework for highly enantioselective heterogeneous asymmetric catalysis[J].Journal of the American Chemical Society,2005,127(12):8940-8941.
[9] He Yabing,Zhou Wei,Qian Guodong,et al.Methane storage in metal-organic frameworks[J].Chemical Society Reviews,2014,43:5657-5678.
[10] Suh M P,Park H J,Thazhe K P,et al.Hydrogen storage in metal-organic frameworks[J].Chemical Reviews,2012,112:782-835.
[11] Murray L J,Dinca M,Long J R.Hydrogen storage in metal-organic frameworks[J].Chemical Society Reviews,2009,38:1294-1314.
[12] Li J R,Kupplera R J,Zhou H C.Selective gas adsorption and separation in metal-organic frameworks[J].Chemical Society Reviews,2009,38:1477-1504.
[13] Li J R,Sculley J,Zhou H C.Metal-organic frameworks for separations[J].Chemical Reviews,2012,112:869-932.
[14] Lin B,Wang H,Chen B.Microporous metal-organic frameworks for gas separation[J].Chem Asian J,2014,9(6):1474-1498.
[15] Adil K,Belmabkhout Y,Renjith S P,et al.Gas/vapour separation using ultra-microporous metal-organic frameworks:insights into the structure/separation relationship[J].Chemical Society Reviews,2017,46:3402-3430.
[16] Zhu Q L,Xia W,Tomoki Akita,et al.Metal-organic framework-derived honeycomb-like open porous nanostructures as precious-metal-free catalysts for highly efficient oxygen electroreduction[J].Advanced Materials,2016,28:6391-6398.
[17] Zhang T,Lin W.Metal-organic frameworks for artificial photosynthesis and photocatalysis[J].Chemical Society Reviews,2014,43:5982-5993.
[18] Dhakshinamoorthy A,Garcia H.Metal-organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles[J].Chemical Society Reviews,2014,43:5750-5865.
[19] Gu Zhigang,Zhan Caihong,Bu Xianhui,et al.Chiral chemistry of metal-camphorate frameworks[J].Chemical Society Reviews,2016,45:3122-3144.
[20] Cui Yuanjing,Yue Yanfeng,Qian G,et al.Luminescent functional metal-organic frameworks[J].Chemical Reviews,2012,112:1126-1162.
[21] Lauren Kreno E,Kirsty Leong,Omar Farha,et al.Metal-organic framework materials as chemical sensors[J].Chemical Reviews,2012,112:1105-1125.
[22] Horike S,Umeyama D,Kitagawa S.Ion conductivity and transport by porous coordination polymers and metal-organic frameworks[J].Accounts Chemical Research,2013,46:2376-2384.
[23] Ramaswamy P,Wong N E,Shimizu George K H,et al.MOFs as proton conductors-challenges and opportunities[J].Chemical Society Reviews,2014,43:5913-5932.
[24] Yoon M,Suh K,Natarajan S,et al.Proton conduction in metal-organic frameworks and related modularly built porous solids[J].Angew Chem Int Ed,2013,52:2688-2700.
[25] Sun L,Campbell M G,Dinca M.Electrically conductive porous metal-organic frameworks[J].Angew Chem Int Ed,2016,55:3566-3579.
[26] Stavila V,Talin A A,Allendorf M D,et al.MOF-based electronic and poto-electronic devices[J].Chemical Society Reviews,2014,43:5994-6010.
[27] Kalidindi S B,Nayak S,Briggs M E,et al.Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering[J].Angew Chem Int Ed,2014,54(1):221-226.
[28] Shyam Biswas,Pascal Van Der Voort.A general strategy for the synthesis of functionalized UiO-66 frameworks:characterization,stability and CO2 adsorption properties[J].Eur J Inorg Chem,2013,12:2154-2160.
[29] He Y F,Seaton N A.Heats of adsorption and adsorption heterogeneity for methane,ethane,and carbon dioxide in MCM-41[J].Langmuir,2006,22(3):1150-1155.
[30] Liu D,Lu K,Poon C,et al.Metal-organic frameworks as sensory materials and imaging agents[J].Inorganic Chemistry,2014,53(4):1916-1924.
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